O. Itoh, N. Iwakoshi, T. Saitoh
1982
Citations
0
Influential Citations
6
Citations
Journal
Bulletin of the Chemical Society of Japan
Abstract
Regio- and stereochemical studies of the solvolyses of various kinds of 2,4-pentanediol derivatives, including 2-acetoxy-4-tosylates, cyclic orthoformates and orthoacetates, have been done and the previously proposed mechanism has been partially revised. The reactions of the proposed intermediate acetoxonium ions with carbanions and with a hydride ion have also been studied.