F. S. Fawcett, C. Tullock, D. D. Coffman
Nov 1, 1962
Citations
1
Influential Citations
104
Citations
Quality indicators
Journal
Journal of the American Chemical Society
Abstract
Carbonyl fluoride is a versatile intermediate to organic fluorine compounds. Its reaction with carbonyl compounds such as cyclohexanone, benzaldehyde and benzophenone gives the gem-difluorides, while N,N-dimethylformamide yields a,a-difluorotrimethylamine. Metal fluoride-catalyzed addition at the ethylenic bond in perfluoroolefins forms perfluoroacyl fluorides, while the C--?! unsaturated compounds CF3X=CF2, CsHsS=CO and CFaC=r': give, respectively, ( CF3)?SCOF, C&?;(COF)? and CF3CF2KCO.