I. Shevchenko, M. Furmanova, V. Kukhar
Feb 1, 1992
Citations
0
Influential Citations
6
Citations
Journal
Zeitschrift für Naturforschung B
Abstract
The methylene-bis(dialkylaminochlorophosphines) 2a and 2b react with N,N′-dimethyl- N,N′-bis(trimethylsilyl)urea 1 to give the 1,5-diaza-2,4-diphosphorinan-6-ones, 4a and 4b, each of which exists as two isomers. Sulfuration of 4a and 4b led to the stable derivatives, 5a and 5b, which, with the help of column chromatography, were separated into pure cis- and trans-isomers. The structures were established, based upon NMR-spectroscopic, chemical and analytical data.