J. Valk, J. Boersma, G. Koten
Dec 13, 1994
Citations
0
Influential Citations
22
Citations
Journal
Journal of Organometallic Chemistry
Abstract
Abstract Several (aryl)trimethylsilane derivatives containing a potentially intramolecularly coordinating dimethylaminomethyl group were prepared and treated with Li 2 PdCl 4 or Pd(OAc) 2 . Highly selective cleavage of the aryl- CSi bond took place to give the corresponding arylpalladium complexes. Similar reactions were observed for benzylic trimethylsilyl compounds. The yields of the reactions with L 2 PdCl 4 varied from 66 to 94%, but yields were > 90% when Pd(OAc) 2 was used.