Stephen A. Sicree, C. Tamborski
Nov 1, 1992
Citations
0
Influential Citations
6
Citations
Journal
Journal of Fluorine Chemistry
Abstract
Abstract Tris(pentafluorophenyl) phosphine and bis (pentafluorophenyl) sulfide react with ethylmagnesium bromide to give products indicating cleavage of the pentafluorophenyl group from phosphorus and sulfur. Ethylated phosphorus and sulfur compounds as well as pentafluorophenylmagnesium bromide are the principal reaction products. Minor products from subsequent reaction between the Grignard reagents and cleavage products have also been detected.