A. Chattopadhyay
Aug 12, 2021
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Abstract
This paper presents the results of a kinetic and product study of the reactions of 3-penten-2-one (3P2) with OH, which relevant to models of biomass burning plume chemistry. The results gave reasonably well characterized rate constants and product yield data, and should eventually be published. They also investigate the kinetics and mechanisms of its oxidation product 2-hydroxy propanal (2HPr) by modeling irradiations of reaction mixtures after it is formed in the experiments with 3P2. The results were used primarily as a means to correct the yield data in the 3P2 experiments for secondary reactions, but also provide a useful addition to the literature, though the results for 2HPr are more uncertain because they are obtained from modeling a complex system.