J. Gilbert, G. Wilkinson
1969
Citations
0
Influential Citations
55
Citations
Journal
Journal of The Chemical Society A: Inorganic, Physical, Theoretical
Abstract
The interactions of dichlorotris(triphenylphosphine)ruthenium(II), RuCl2(PPh3)3, with various reagents have been studied and the resulting complexes characterised by i.r. and n.m.r. spectroscopy.The new complexes comprise those of nitriles, RuCl2(RCN)2(PPh3)2, amines, RuCl2(amine)2(PPh3)2, β-diketonates, Ru(β-diket)2(PPh3)2, carboxylates, Ru(OCOR)2(PPh3)2, the halogen bridged dimer [RuCl2(PPh3)2]2 and its acetone solvate and chloro-π-cyclopentadienylbis(triphenylphosphine)ruthenium(II).