A. Kufelnicki, M. Świątek, M. Woźniczka
Jan 6, 2016
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Influential Citations
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Journal
Journal of Solution Chemistry
Abstract
The coordinating properties in aqueous solution of two novel pyridine-4-methylene derivatives, diethyl(pyridine-4-ylmethyl)phosphate (4-PO(Oet)2CH2-py = 4-pmOpe) and 4-pyridylmethylphos phonic acid (4-PO(OH)2CH2-py = 4-pmpa), towards Cu(II) are compared with those of 4-hydroxymethyl-pyridine (4-OHCH2-py = 4-pmOH). The two new derivatives were chosen due to their expected interesting biological activity that is observed for related solid complexes of several metals with various pyridine-methylene derivatives. The studies were carried out using pH potentiometry, UV–Vis spectrophotometry and EPR spectroscopy. The results show that 4-pmOpe and 4-pmpa, similarly to 4-OHCH2-py, form mononuclear L:M = 1:1 and 2:1 complexes with Cu(II). However, in the case of 4-pmpa, complexation occurs both via oxygen atoms of the R-$$ {\text{PO}}_{3}^{2 - } $$PO32- group (ML and ML2 species) and the N(1) nitrogen (protonated MLH and ML2H2 complexes). The possible attendance of the third ligand in the coordination sphere was indicated for 4-OHCH2-py by EPR spectroscopy.