J. Yadav, A. J. Reddy, K. S. Shankar
Mar 14, 2013
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Influential Citations
7
Citations
Journal
Synthesis
Abstract
Abstract The concise total synthesis of helicascolides A, B, and C has been achieved in seven steps starting from commercially available tiglic aldehyde [(E)-2,3-dimethylacrylaldehyde]. Oppolzer’s sultam aldol, Mukaiyama aldol, and Dess–Martin periodinane oxidation reactions are the key steps involved in the target synthesis.