S. Schei, R. Stōlevik
Apr 1, 1985
Citations
0
Influential Citations
16
Citations
Journal
Journal of Molecular Structure
Abstract
Abstract The conformational composition obtained for 1,2-dichloropropane at 26°C was 74% of the anti (A) conformer and 26% of the gauche (G −1 with error limits ± 7%. For 1,2-dibromopropane the conformational composition at 40°C was 85% A , 4% G − and 11% G + with error limits ±6%. Normal values of the structural parameters were determined. The results from the molecular-mechanics calculations agree with the electron diffraction data. The values of the low-frequency torsional XH 2 CC vibrations have been compared with observations form vibrational spectroscopy.