M. Arias, E. Gálvez, B. Rico
Mar 1, 1990
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Influential Citations
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Citations
Journal
Journal of Molecular Structure
Abstract
Abstract 8-Phenethyl-8-azabicyclo[4.3.1]decan-10α -ol has been studied by 1H-NMR at 500 MHz. To assist the unambiguous assignment of bicyclic system protons, hom o nuclear 2D COSY spectrum has been performed. In (CD3)2SO solution, this azabicyclanol can be described through an equilibrium between two conformers in which the piperidine ring adopts a slight flattened chair form with the OH and the N-phenethyl groups in equatorial positions and the cycloheptane moiety a twist-chair conformation.