R. Okazaki, M. Unno, N. Inamoto
Mar 1, 1989
Citations
0
Influential Citations
4
Citations
Journal
Chemistry Letters
Abstract
Dynamic NMR and molecular mechanics calculations show that 1-bromo-2,4,6-tris[bis(trimethylsilyl)methyl]benzene exists as a conformer where both o-methine hydrogens are coplanar with the ring and directed toward the bromine. Relevance of this conformation with unique properties of Tb as a steric protection group is also described.