M. Arias, E. Gálvez, M. Izquierdo
Oct 1, 1986
Citations
0
Influential Citations
25
Citations
Journal
Journal of Molecular Structure
Abstract
Abstract N-Substituted 8-azabicyclo[3.2.1]octan-3-ones have been studied by 1H and 13C NMR spectroscopy. In CDCl3 solutions, these ketones display the same preferred conformation. The pyrrolidine and piperidone rings adopt a flattened N-8 envelope and distorted chair conformation, puckered at N-8 and flattened at C-3, respectively, with the N-substituent in axial position with respect to the piperidone ring.