S. Chandrasekhar, C. Roy
1994
Citations
0
Influential Citations
17
Citations
Journal
Journal of The Chemical Society-perkin Transactions 1
Abstract
The Baeyer–Villiger reaction of 2-(2-oxocyclohexyl)acetic acid occurs via a bicyclic Criegee intermediate, which fragments with stereoelectronic control, as evidenced by product analysis; the reaction of the-but-2-yl ester and of 2-(2-oxocyclopentyl)acetic acid also show evidence of such stereoelectronic control, but less convincingly.