S. Panda, R. Jat, Amir Fayaz
Jun 1, 2020
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Influential Citations
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Journal
New Journal of Chemistry
Abstract
4-Arylpyrazole-decorated dibenzothiophenes have been synthesized. The synthesis involves the treatment of 2,8-dibromodibenzothiophene with pyrazole under Ullmann-type amination conditions for the dual C–N bond formation. The selective bromination of the resulting dual C–N bonded 2,8-dipyrazolyldibenzothiophene, and the subsequent Suzuki–Miyaura reaction furnished the target conjugated materials comprising small organic molecules. The electron-deficient dibenzothiophene-S,S-dioxide core was obtained in quantitative yield. UV-Vis absorption studies indicated changes in the positions of the peak maxima upon increasing the conjugation length. Electrochemical and theoretical investigations of selected synthesized materials are also included.