N. Ishida, D. Nečas, Yusuke Masuda
Jun 15, 2015
Citations
0
Influential Citations
24
Citations
Journal
Angewandte Chemie
Abstract
3-Hydroxypiperidine scaffolds were enantioselectively constructed in an atom-economical way by sequential action of light and rhodium upon N-allylglyoxylamides. In a formal sense, the allylic C-H bond was selectively cleaved and enantioselectively added across the ketonic carbonyl group with migration of the double bond (carbonyl-ene-type reaction).