C. Mukai, Jin Sung Kim, M. Uchiyama
Oct 22, 1998
Citations
0
Influential Citations
17
Citations
Journal
Tetrahedron Letters
Abstract
Abstract The Pauson-Khand reaction of the (3S,4S)-3,4-bis(tert-butyldimethylsilyloxy)-7-octen-1-yne derivatives, derived from (+)-diethyl tartrate, exclusively gave the (2S,3S,6S)-2,3-bis(tert-butyldimethylsilyloxy)bicyclo[4.3.0]non-1(9)-en-8-one derivatives, while the (3S,4S)-3,4-dihydroxy-7-octen-1-yne congeners diastereocomplementarily afforded the corresponding (2S,3S,6R)-2,3-dihydroxy-bicyclo[4.3.0]non-1(9)-en-8-one in a highly selective manner.