Masaru Okutani, Y. Mori
Jan 2, 2009
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Influential Citations
82
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Quality indicators
Journal
The Journal of organic chemistry
Abstract
Tetra-n-butylammonium fluoride was found to be a mild and efficient base for the elimination reaction of bromoalkenes. Treatment of 1,1-dibromoalkenes, (Z)-1-bromoalkenes, and internal bromoalkenes with 5 equiv of TBAF x 3H2O in DMF yielded terminal and internal alkynes in high yields without undue regard to the presence of water.