Priyabrata Ghana, F. D. van Krüchten, T. Spaniol
Mar 12, 2019
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0
Influential Citations
18
Citations
Journal
Chemical communications
Abstract
By using a triaryl-Tren ligated titanium dinitrogen complex, K2[{(Xy-N3N)Ti}2(μ2-N2)] (3), prepared by two-electron reduction of [TiCl(Xy-N3N)] (1-Cl) under N2 atmosphere, catalytic fixation of molecular nitrogen to form tris(trimethylsilyl)amine was achieved under ambient conditions with a turnover number (TON) of up to 16.5 per titanium atom.