Grégoire Le Corre, H. Grützmacher
Feb 10, 2022
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0
Influential Citations
1
Citations
Journal
Dalton transactions
Abstract
A reaction of trisodium phosphide (Na3P) with chlorosilanes allows for simple derivatization into silyl- and cyano-substituted phosphanide species which were compared with each other. The recently discovered cyano(triphenylsilyl)phosphanide shows unique coordination properties compared to bis(silyl)phosphides.