M. Beckett, D. P. Cassidy, A. Duffin
Nov 15, 1991
Citations
0
Influential Citations
13
Citations
Journal
Inorganica Chimica Acta
Abstract
Abstract Bis(3-aminopropyl)phenylphosphine (bap) has been reacted with fac -[{PtMe 3 I} 4 ] in CHCl 3 solution to yield fac -[PtMe 3 (bap)]I which has the bap ligand tridentate NNP. Metathesis of fac -[PtMe 3 (bap)]I with Na[BPh 4 ] in thf solution results in fac -[PtMe 3 (bap)][BPh 4 ]. Bap is also NNP tridentate in the Group 6 metal(0) complexes fac -[Mo(CO) 3 (bap)] and fac -[W(CO) 3 (bap)], prepared from the reactions of bap with cis -[M(CO) 4 (pip) 2 ] (M = Mo, W). The new complexes have been characterized by melting point, elemental analysis, and by IR and multielement ( 1 H, 11 B, 31 P) NMR spectroscopy.