A. Sinha, J. L. Jain, B. K. Sinha
1984
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Influential Citations
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Journal
Synthesis and Reactivity in Inorganic and Metal-organic Chemistry
Abstract
Abstract Complexes of the types [NiL2 X 2], L = 3-methyl-isothiazole (3-MIT) and 5-methylisothiazole (5-MIT), X = Cl, Br, [NiL4 X 2], L = 4-methylisothiazole (4-MIT) and 5-methlisothiazole, X = Cl, Br and [NiL6] (Clo4)2 L = 4-methylisothiazole and 5-methylisothiazole have been prepared and characterised on the basis of analytical, electrical conductivity, magnetic moment, electronic and infrared spectral data. Ligand field parameters for all these complexes as well as [Ni(isothiazole)6] (Clo4)2 have been evaluated and the position of isothiazoles in the spectrochemical series has been established. All the complexes are bonded through the N-atom.