Shu’ni Li, Q. Zhai, Mancheng Hu
May 1, 2010
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0
Influential Citations
3
Citations
Journal
Zeitschrift für anorganische und allgemeine Chemie
Abstract
Two new coordination polymers, [Na(H2L)(H2O)2]n (1) and [Ba(H2L)2(H2O)]n (2) (H3L = 3-formyl-4-hydroxybenzenesulfonic acid) were synthesized and structurally characterized. The H2L– ligand shows three different bridging modes, μ3 in 1, μ3 and μ4 in 2. Compound 1 presents a 2D pillared structure, whereas 2 forms a 3D framework. Both 1 and 2 show blue luminescence at 380 nm in aqueous solution, however, their solid state emissions are at 406 and 446 nm, respectively.