J. Kopeček
Aug 1, 1977
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0
Influential Citations
75
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Journal
Macromolecular Chemistry and Physics
Abstract
Reactive copolymers of N-(2-hydroxypropyl)methacrylamide (1) with p-nitrophenyl esters of N-methacryloylglycyl-L-leucine (3a), N-methacryloylglycyl-L-phenylalanine (3b), N-methacryloyl-e-aminocaproyl-L-leucine (7a), and N-methacryloyl-e-aminocaproyl-L-phenylalanine (7b) (i.e. copolymers 8–11) were synthesized. The polymers thus obtained were characterized by the content of active groups, by intrinsic viscosity [η], and by the rate constant of aminolysis with tert-butylamine in dimethyl sulfoxide. Polymers containing free NH2 groups were prepared by a polymeranalogous reaction with diamines, predominantly 1,6-hexanediamine. The effect of the copolymer structure, of diamine, and of the reaction conditions on the course of the polymeranalogous reaction was studied.