Jessy Aziz, G. Frison, M. Gómez
Nov 13, 2014
Citations
0
Influential Citations
33
Citations
Journal
ACS Catalysis
Abstract
An original formation of one C–N bond and one C–C bond on the same carbenic center has been developed. This approach involves a copper-catalyzed cross-coupling reaction between 2′-bromo-biaryl-N-tosylhydrazones and different amines leading to 9H-fluoren-9-amine derivatives. This reaction proceeds under mild conditions in glycerol, an inexpensive and environmentally friendly solvent, without adding any external ligand.