L. Tran, I. Popov, O. Daugulis
Oct 29, 2012
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Influential Citations
459
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Journal
Journal of the American Chemical Society
Abstract
An auxiliary-assisted, copper catalyzed or promoted sulfenylation of benzoic acid derivative β-C-H bonds and benzylamine derivative γ-C-H bonds has been developed. The method employs disulfide reagents, copper(II) acetate, and DMSO solvent at 90-130 °C. Application of this methodology to the direct trifluoromethylsulfenylation of C-H bonds was demonstrated.