Gideon J. J. Steyn, A. Roodt, I. Poletaeva
May 30, 1997
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0
Influential Citations
42
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Journal
Journal of Organometallic Chemistry
Abstract
Abstract The crystal structure of (methyl 2-(amino)-1-cyclopentene-1-dithiocarboxylato- κN , κS )-carbonyl(triphenylphosphine)rhodium(I), [Rh(hacsm)(CO)(PPh 3 )], was determined. The complex crystallizes in the monoclinic space group P 2 1 / c with a = 16.430(1), b = 9.930(1), c = 17.194(1) A, β = 90.72(1)°, Z = 4, R = 2.89% from refinement of 3143 reflections. The structural data obtained by this study were correlated with 31 P and 13 C NMR data measured for different [Rh(L,L′-BID)(CO)(PPh 3 )] complexes (L,L′-BID = monocharged bidentate ligand with donor atoms L, L′: variations of oxygen, nitrogen and sulphur). A good correlation between 1 J ( 31 P- 103 Rh) and the Rh-P bond distance was obtained.