Ka-Ho Ng, Zhongyuan Zhou, Wing-Yiu Yu
Jul 11, 2013
Citations
0
Influential Citations
67
Citations
Journal
Chemical communications
Abstract
Rh(III)-catalyzed aromatic C-H amination of acetophenone o-methyloximes with primary N-chloroalkylamines was developed, and the arylamine products were obtained in up to 92% yield. The reaction probably involves rate-limiting electrophilic C-H bond cleavage (kH/kD = 2).