I. Wawrzycka-Gorczyca, B. Rzeszotarska, A. Dżygiel
Jul 1, 2003
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Influential Citations
4
Citations
Journal
Zeitschrift für Kristallographie - Crystalline Materials
Abstract
Abstract The analysis of molecular structures of three derivatives: 5-amino-3-carbomethoxy-1-methyl-1H-[1,2,4]-triazole (1), 1-acetyl-5-amino-3-carbomethoxy-1H-[1,2,4]-triazole (2) and 5-acetylamino-3-carbomethoxy-1-methyl-1H-[1,2,4]triazole (3) indicate the sensitivity of the N2–N1–C5 fragment of the triazole ring to the substitution. Molecular conformations are influenced by several intra- and intermolecular contacts. In all structures very extensive N–H···N/O and C–H(methyl)···O/N net of secondary interactions is formed. This kind of interactions is common in crystal structures which are proton-deficient and for this reason various types of multi-point interactions are forced. Besides, triazole π···π stacking interactions are observed.