J. Du, Guiming Wei, Jinling He
Aug 1, 2006
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Journal
Materials Letters
Abstract
Abstract A novel butane-1,4-diamine-bridged copper(II) compound was synthesized via solvent diffusion route with high yield. Each copper is coordinated by four butane-1,4-diamine ligands, each of which in turn links with two copper atoms to form a two-dimensional (2D) square network. Interestingly, the title compound features a cross-linking rhombic channel (ca. 5.06 × 14.73 A) parallel to the crystallographic b axis. And magnetic result measured indicates the presence of localized unpaired electrons in the structure and thus the cupric Cu(II) state.