E. Schaumann*, C. Friese, G. Adiwidjaja
1989
Citations
0
Influential Citations
8
Citations
Journal
Tetrahedron
Abstract
Abstract Vinylsilanes 1d-h react with chloro(phenylthio)carbene 2 to give functionalized silylcyclo-propanes 3 with high Z-stereoselectivity. For 3g, the relative configuration was proven by an X-ray structural analysis. Synthetic modifications of 3 include elimination, oxidation, and substitution to give products 5, 6, and 7a-f, respectively.