B. Salem, Estelle Delort, P. Klotz
Jun 6, 2003
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0
Influential Citations
31
Citations
Journal
Organic Letters
Abstract
Several bicyclic compounds bearing a 1,2-cyclopentanediol have been prepared from various anti- or syn-γ-bromopropargylic diols and cis-dioxolanes under palladium(0) catalysis. The reaction proceeds through a 5-exo-dig cyclocarbopalladation. When the corresponding trans-dioxolanes are used, the only products isolated are obtained from a direct Stille cross-coupling reaction.