Heinrich Rimml, L. Venanzi
Dec 13, 1983
Citations
0
Influential Citations
61
Citations
Journal
Journal of Organometallic Chemistry
Abstract
It is shown that 1,3-bis(diphenylphosphinomethyl)benzene (PCHP) readily undergoes a cyclometallation reaction with nickel(II), palladium(II), and platinum(II) species giving products of the type [MX(PCP)] [M Ni, Pd, and Pt; X halide and PCP 2,6-bis(diphenylphosphinomethyl)phenyl]. Cyclometallation requires the formation of intermediates trans-[MX2(PCHP)].