P. Jutzi, U. Siemeling
Sep 20, 1995
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Journal
Journal of Organometallic Chemistry
Abstract
Abstract The coordination chemistry of cyclopentadienyl ligands bearing either a dimethylaminoethyl side-chain or a pendant pyridyl group is described. The influence of these N donor functionalities on the structure and the physical as well as chemical properties of relevant metal complexes is discussed. In several cases, a relatively weak intramolecular coordination of the pendant amine is found; the hemilabile coordination profile of the N functionalised cyclopentadienyl ligands towards d-block elements may prove useful for the development of single-component catalysts.