A. Nishimura, M. Ohta, H. Kato
May 1, 1970
Citations
0
Influential Citations
5
Citations
Journal
Bulletin of the Chemical Society of Japan
Abstract
The deamination of methylenecyclopropylcarbinylamine, prepared from ethyl methylenecyclopropanecarboxylate via the corresponding amide, gave acetylcyclopropane, methylenecyclopropylcarbinol, and 3-methylenecyclobutanol. On the basis of these results and the deuterium distribution of the deamination products of methylenecyclopropylcarbinylamine-α,α-d2, the homoallylic (III) and cyclopropylvinyl (VIII) cations are proposed as intermediates.