E. A. Chernyshev, O. V. Kuz’min, A. Lebedev
Oct 1, 1984
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Journal
Bulletin of the Academy of Sciences of the USSR, Division of chemical science
Abstract
Conclusions1.The thermal decomposition of 1-trimethylsilyl-μ3-S,S-ethylenedithiolatohexacarbonyldiiron leading to the formation of trimethylvinylsilane, CO and FeS is accompanied by partial desilylation with the formation of ethylene and propylene.2.The pyrolysis of the dithiolane diiron hexacarbonyl complex of trimethylvinylsilane in the presence of HCl proceeds with significant desilylation of the starting complex and formation of 1,1-dichloroethane, 1,1-dichloropropane, butanedithiol, and hexanedithiol.