P. Pichat
1997
Citations
1
Influential Citations
30
Citations
Quality indicators
Journal
Water Science and Technology
Abstract
Pyridine, 1-2-dimethoxybenzene, morpholine and lindane are mineralized by the TiO 2 -UV process. In the studies briefly reviewed here, their intermediate products, in particular the aliphatics, were identified both to determine what are the compounds that may be left in the treated water and to increase our understanding of the photocatalytic pathways. In addition to the oxidation and cleavage of the bonds, H(Cl) atom addition (or transfer) and coupling reactions were found to occur, which illustrates the complexity of photocatalytic degradations. Moreover, a comparison of the primary products of quinoline degraded either by photocatalysis or by the photo-Fenton process (Fe ions-H 2 O 2 -UV) showed that OH° radicals are not the only active species involved in photocatalytic degradations. From the effects of adding superoxide dismutase, it was inferred that in situ formed O 2 −o anion-radicals intervene chemically, possibly by reacting with quinoline cation-radicals generated via electron transfer from quinoline to TiO 2 .