S. Berger
1978
Citations
0
Influential Citations
10
Citations
Journal
Tetrahedron
Abstract
Abstract 2-Azabicyclo(2.2.2)octan-3-One 1, N-isopropylpivaloylamide 2 and 4-azatricyclo(4.3.1.13,8)undecan-5-one 3 have been prepared with a 15N label. The amides were reduced to the corresponding amines 2-azabicy-clo(2.2.2)octane 4, N-isopropyl-N-neopentylamine 5 and 4-azatricyclo(4.3.1.13,8)undecane 6. The 13C spectra of these compounds and their hydrochlorides were measured and the 15N13C spin coupling constants interpreted in terms of their conformational dependence.