R. Cea-Olivares, O. J. Sandoval, G. Espinosa-Pérez
1994
Citations
0
Influential Citations
31
Citations
Journal
Polyhedron
Abstract
Abstract Di- and triorganotin(IV) derivatives of 1-phenyl-1H-tetrazole-5-thiol, RnSn(SCN4Ph)4−n (R = Me, Bz; n = 2, 3), were prepared by reacting the corresponding organotin chlorides with the ammonium salt of the thiotetrazolato anion. The title compounds were characterized by means of IR and 1H, 13C and 119Sn NMR spectroscopy. The molecular structure of Bz3SnSCN4Ph was investigated using X-ray diffractometry. Data on a redetermination of the crystal and molecular structures of n-Bu2Sn(SCN4Ph)2 are also included, and a comparative discussion of the two structures is presented.