S. Tamagaki, K. Sakaki, S. Ōae
Dec 1, 1974
Citations
0
Influential Citations
19
Citations
Journal
Bulletin of the Chemical Society of Japan
Abstract
Thiocarbonyl S-imide of 4,5-benzo-1,2-dithiole-3-thione reacted with primary and secondary amines of various types to give both rearranged and amine-exchanged imines. By kinetical studies a plausible mechanism involving the addition and elimination of amine on the tetravalent sulfur atom was proposed.