Alisha M. Bohnsack, Ilich A. Ibarra, V. Bakhmutov
Oct 16, 2013
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Journal
Journal of the American Chemical Society
Abstract
MCl2 complexes of a new p-carboxylated 1,2-bis(diphenylphosphino)benzene ligand are effectively utilized as tetratopic building blocks to prepare isostructural porous coordination polymers with accessible reactive metal sites (M = Pd, Pt). The crystalline materials exhibit unusual and fully reversible H2 sorption at 150 °C. Post-synthetic reactivity is also possible, in which Pt-Cl bonds can be activated to provide organometallic species in the pores.