A. Izumi, Ryoji Nomura, T. Masuda
May 15, 2001
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0
Influential Citations
56
Citations
Journal
Macromolecules
Abstract
Poly(p-phenyleneethynylene)- and heteroaromatic-containing poly(phenylene)-based conjugated polymers having photoisomerizable azobenzene units in the main chain were prepared using palladium-catalyzed cross-coupling reaction of 4,4‘-diiodoazobenzenes with 1,4-diethynylbenzenes and bis(trimethylstannyl)heteroaromatics, respectively. Polymers possessing n-hexyl side chains on the aromatic rings were soluble in common organic solvents such as tetrahydrofuran, chloroform, and toluene. The polymers were thermally stable in air (T0 > 330 °C). Poly(p-phenyleneethynylene)-based polymers (3) and thiophene-, furan-, and N-methylpyrrole-containing poly(phenylene)-based polymers (5) showed remarkably red-shifted absorptions in the visible region (λmax > 400 nm) due to the extended main-chain conjugation, while the pyridine-containing poly(phenylene)-based polymer (5d) possesses a low degree of main-chain conjugation (λmax < 380 nm). Polymer 5d with low degree of main-chain conjugation showed reversible photoisomeriza...