Yifeng Cao, Qiwei Yang, Huabin Xing
Dec 1, 2014
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Influential Citations
7
Citations
Journal
Chinese Journal of Chemical Engineering
Abstract
Abstract The solubility of nonivamide in dimethyl sulfoxide, methanol, acetone, ethyl acetate, methyl tert -butyl ether, acetonitrile, n -hexane and water over the temperature range of 293.2 K to 323.2 K was measured. The results reveal that the solubility of nonivamide is greatly influenced by the hydrogen-bond basicity of solvent and increases with temperature. The experimental data were correlated with the modified Apelblat equation. The dissolution enthalpy and entropy of nonivamide in different solvents were obtained from the correlation of ln x with 1/ T using the van't Hoff equation. The calculated nonivamide solubility is in good agreement with experimental data for most of the solvents.