H. Hori, T. Nakajima, Y. Nishida
Dec 1, 1986
Citations
0
Influential Citations
13
Citations
Journal
Journal of Carbohydrate Chemistry
Abstract
Abstract Photobromination and the succeeding deuteration with tri-n-butyltindeuteride were performed on eight l,6-anhydro-2,3,4-tri-O-benzoylhexopyranoses to give C-6 chirally deuterated hexopyranoses. The stereochemistry of these two reactions are discussed in terms of steric effects of substituents at C-2, C-3 and C-4 of 1,6-anhydrohexopyranoses.