Md. Serajul Haque Faizi, Sahid Hussain
May 3, 2014
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Influential Citations
11
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Journal
Acta Crystallographica Section E: Structure Reports Online
Abstract
In the mononuclear title complex, [HgCl2(C20H21N3)], synthesized from the quinoline-derived Schiff base N 1,N 1-diethyl-N 4-(quinolin-2-ylmethylidene)benzene-1,4-diamine (QMBD), the coordination geometry around the Hg2+ atom is distorted tetrahedral, comprising two Cl atoms [Hg—Cl = 2.3654 (19) and 2.4394 (18) Å] and two N-atom donors from the QMBD ligand, viz. one imine and quinoline [Hg—N = 2.334 (5) and 2.340 (5) Å, respectively]. In the crystal, weak C—H⋯Cl hydrogen bonds and weak π–π aromatic ring stacking interactions [minimum ring-centroid separation = 3.680 (4) Å] give an overall three-dimensional network.