B. Arbuzov, L. K. Yuldasheva
Oct 1, 1962
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Journal
Russian Chemical Bulletin
Abstract
1. Dipole moment data shows that 1,3-dioxane and its substituted forms containing nonpolar substituents at the second carbon atom have the armchair configuration. 2. The molecules of 2-bromomethyl-1,3-dioxane and 2-ethoxy-4-methyl-1,3-dioxane have the armchair configuration with the polar groups in the equatorial position. Free rotation of the CH2Br groups is possible in the case of 2-bromomethyl-1,3-dioxane.