B. Benner, S. Wise, L. Currie
Sep 1, 1995
Citations
11
Influential Citations
150
Citations
Quality indicators
Journal
Environmental science & technology
Abstract
As part of the United States Environmental Protection Agency's Integrated Air Cancer Project, air particulate matter samples collected in Boise, ID, were analyzed by gas chromatography with mass spectrometric detection (GC-MS) and apportioned between their two main sources : residential wood combustion (RWC) and motor vehicle (MV) emissions. The technique used for distinguishing the source contributions involved comparison of the concentration of 1,7-dimethylphenanthrene (1,7-DMP), a polycyclic aromatic hydrocarbon (PAH) emitted primarily by burning soft woods (e.g., pines), with that of a PAH emitted in modest concentrations by both RWC and MV sources, 2,6-dimethylphenanthrene (2,6-DMP). These results were then compared with the mean 1,7-DMP/2,6-DMP ratio of 48 samples collected in a roadway tunnel, with any enrichment in the Boise sample ratios over the mean tunnel ratio attributable to the RWC source. These resulting RWC contributions were compared with fraction RWC results obtained by radiocarbon measurements ( 14 C/ 13 C) of the same extracts from Boise, with generally good correlations between the two techniques observed, suggesting that the methods are comparable when used to distinguish emissions of MVs from RWC of soft woods.