M. Munakata, J. Zhong, T. Kuroda–Sowa
Dec 1, 2001
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Journal
Inorganic chemistry
Abstract
A novel silver(I) coordination polymer of 1-methylpyrene (mpyr) with double-decker motifs, {[Ag2(mpyr)2(ClO4)2]0.5benzene}n (1), was synthesized and characterized. Polymer 1 consists of 1-D double-decker chains, which are formed by dimeric double-decker units ([Ag(mpyr)(ClO4)]2) through the linkage of the perchlorate groups. In addition, the dimeric moieties between the adjacent chains are stacked to lead to column π−π stacks. Therefore, complex 1 can also be regarded as a 2-D stacking polymer. The effects of substituting groups, and other factors, on the structure of silver(I) complexes with polycyclic aromatic hydrocarbons are also discussed.