A. Protsenko, O. Shakirova, A. E. Protsenko
Apr 28, 2021
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Influential Citations
2
Citations
Journal
Journal of Molecular Structure
Abstract
Abstract New coordination compounds of copper(II) and cobalt(II) with 3-(chloromethyl)pyridine hydrochloride (HL1)Cl and 2-(chloromethyl)pyridine hydrochloride (HL2)Cl of the following composition: (HL1)2[CuCl4] (1), (HL1)2[CoCl4] (2), (HL2)2[CuCl4] (3) and (HL2)2[CoCl4] (4) have been synthesized. The compounds have been investigated by single-crystal X-ray diffraction, simultaneous TGD the structures show the formation of a halogen bond between Cl of the anion and Cl of adjacent cations. The melting temperatures, as well as the melting enthalpy and thermal stability intervals of ionic liquids were found.