H. Imura, S. Matsumora, N. Suzuki
Feb 1, 1986
Citations
0
Influential Citations
5
Citations
Journal
Bulletin of the Chemical Society of Japan
Abstract
Partition coefficients of dimethyldithiocarbamic acid and its copper(II) chelate have been determined in various organic solvents −0.10 mol dm−3 aqueous perchlorate solution systems at 25 °C. The effects of inert organic solvents are explained with the aid of the regular solution theory. Also, a linear free-energy relationship between the partition coefficient of the copper(II) chelate and that of the reagent is demonstrated. The partition coefficient of the copper(II) chelate is compared with that of bis(2,4-pentanedionato)copper(II) and various factors governing the partition coefficients of these chelates are discussed with the aid of the scaled particle theory.